Project A11

Bismuth(III)iodide as a 2D Material for Hybrid Compounds

Dr. Johanna Heine

Philipps-Universität Marburg

Department of Chemistry

Hans-Meerwein-Straße, 35032 Marburg
Phone: +49 6421 28-25527
Fax: +49 6421 28-25653
Email: johanna.heine@chemie.uni-marburg.de

Expertise

Inorganic synthesis, hybrid materials, X-ray diffraction, spectroscopic characterization (UV-visible/luminescence), thermogravimetric analyses

University Education

2011 Doctoral degree in Chemistry (Dr. rer. nat.), Philipps-Universität Marburg, Advisor: Prof. S. Dehnen
2008 Diploma degree in Chemistry (Dipl. Chem.), Philipps-Universität Marburg, Supervisor: Prof. S. Dehnen
2002-08 Studies in Chemistry (Philipps-Universität Marburg)

Professional Experience

2013 Junior group leader in Chemistry (Philipps-Universität Marburg)
2012-13 Postdoc, Universität Würzburg, (Advisor: Prof. K. Müller-Buschbaum)

Honours, Awards and other Proofs of Qualification

2012 Postdoc-Scholarship from the State of Bavaria

Selected Publications

  1. J. Heine, J. Schmedt auf der Günne, S. Dehnen, Formation of a Strand-Like Polycatenane of Icosahedral Cages for reversible One-Dimensional encapsulation of Guests, J. Am. Chem. Soc. 133, 10018 (2011).
  2. J. Heine, T. Wehner, R. Bertermann, A. Steffen, K. Müller-Buschbaum, [Bi2Cl6(pyz)4]: A 2D-Pyrazine Coordination Polymer As Soft Host Lattice for the Luminescence of the Lanthanide Ions Sm3+, Eu3+, Tb3+ and Dy3+, Inorg. Chem. 53, 7197 (2014).
  3. J. Heine, A Step Closer to the Binary: The [Bi6I20]2- Anion, Dalton Trans. 44, 10069 (2015).
  4. Santner, J. Heine, S. Dehnen, Synthesis of Crystalline Chalcogenides in Ionic Liquids, Angew. Chem. Int. Ed. 54, 886 (2016).
  5. B. Wagner, N. Dehnhardt, M. Schmid, B. P. Klein, L. Ruppenthal, P. Müller, M. Zugermeier, J. M. Gottfried, S. Lippert, M.-U. Halbich, A. Rahimi-Iman, J. Heine, Color Change Effect in an Organic-Inorganic Hybrid Material based on a Porphyrin Diacid, J. Phys. Chem. C 120, 28363 (2016).
  6. N. Heidary, A. Beyer, K. Volz, J. Heine, Towards the liquid phase exfoliation of bismuth iodide, Dalton Trans. 46, 8359 (2017).
  7. N. Dehnhardt, J.-N. Luy, M. Szabo, M. Wende, R. Tonner, J. Heine, Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations, Chem. Commun. 55, 14725 (2019).
  8. N. Dehnhardt, M. Axt, J. Zimmermann, M. Yang, G. Mette, J. Heine, Band-Gap Tunable, Chiral Hybrid Metal Halides Displaying Second Harmonic Generation, Chem. Mater. 32, 4801 (2020).
  9. B. Wagner, A. Huttner, D. Bischof, A. Engel, G. Witte, J. Heine, Chemical Surface Reactivity and Morphological Changes of Bismuth Triiodide under Different Environmental Conditions, Langmuir 36, 6458 (2020).
  10. N. Dehnhardt, J.-N. Luy, P. Klement, L. Schipplick, S. Chatterjee, R. Tonner, J. Heine, Mixed Group 14-15 Metalates As Model Compounds For Doped Lead Halide Perovskites, Angew. Chem. Int. Ed. (accepted) (2020), DOI:10.1002/anie.202014696.